Total synthesis of natural (+)-duocarmycin SA

DOI: 10.1248/cpb.43.1064

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1064 - 1066 (1995)

Update date:2022-09-26

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Authors:

Muratake

Matsumura

Natsume Natsume

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Article abstract of DOI:10.1248/cpb.43.1064

A total synthesis of natural (+)-duocarmycin SA (1) was achieved as shown in Chart 1, starting from L-malic acid (5) by using a Lewis acid-mediated indole formation reaction of a pyrrole precursor 14 to form the key compound 15.

Full text of DOI:10.1248/cpb.43.1064

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