Anomalous reactivity of triphenylarsine and triarylphosphines of low basicity with [Ir(cod)(py) 2][PF6] and use of the complexes as precatalysts for imine hydrogenation

DOI: 10.1016/S0022-328X(96)06627-2

Source and publish data:

Journal of Organometallic Chemistry p. 75 - 82 (1997)

Update date:2022-08-04

Topics:

Authors:

Bedford, Robin B.

Chaloner, Penny A.

Dewa, Shaliza Z.

Lopez, Gregorio

Hitchcock, Peter B.

Momblona, Francisca

Serrano, Jose L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(96)06627-2

Reaction of [Ir(cod)(py)₂][PF₆] with PPh₃ or P(C₆H₄-4-F)₃ gives the bis(phosphine) derivative [Ir(cod)L₂][PF₆], but with the poorly basic phosphine P(C₆H View More

Full text of DOI:10.1016/S0022-328X(96)06627-2

Products guided by the article

Product name:[Ir(tris(4-fluorophenyl)phosphine)2(1,5-cyclooctadiene)]PF₆

Cas No:167545-40-6

R&D Labs maybe for 167545-40-6

xujianqiang

Contact:86-21-57725962

Address:shanghai
Shanghai Taibao Pharmaceutical Technology Co., Ltd(expird)

Contact:021-52217366

Address:shanghai
MiHecb Bio-Tech Co., Ltd.

Contact:+86-0592 5353131

Address:No.56 Guani Road Software Park 2,Siming District
AURORA CHEMICAL CO., LTD

Contact:86-532-68629711 13780605697

Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Wudi Reaction Pharma&Chemical Co.,Ltd.

website:http://www.ruixinchem.com/

Contact:86-543-2257986

Address:Xinhai Industrial Zone, Wudi County,Shandong Province,China.

Relevant to this article

Stereoselective reactions of chiral amines with racemic chlorophosphines

Doi:10.1080/10426500490459650
(2004)
A vinylzirconation reaction of alkynes

Doi:10.1021/ja00126a035
(1995)
Oxidative aromatization of 1,3,5-trisubstituted pyrazolines using hydrogen tetrachloroaurate as catalyst under an oxygen atmosphere

Doi:10.1080/00304940902956119
(2009)
In search of new chemical entities with spermicidal and anti-HIV activities

Doi:10.1016/S0968-0896(99)00188-1
(1999)
Novel ipso-Substitution of p-Sulfinylphenols through the Pummerer-Type Reaction: A Selective and Efficient Synthesis of p-Quinones and Protected p-Dihydroquinones

Doi:10.1021/jo970418o
(1997)
A Practical Synthesis of the Platelet Fibrinogen Antagonist, Elarofiban

Doi:10.1021/op034103o
(2003)

Article Doi