Anomalous reactivity of triphenylarsine and triarylphosphines of low basicity with [Ir(cod)(py) 2][PF6] and use of the complexes as precatalysts for imine hydrogenation

DOI: 10.1016/S0022-328X(96)06627-2

Source and publish data:

Journal of Organometallic Chemistry p. 75 - 82 (1997)

Update date:2022-08-04

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Authors:

Bedford, Robin B.

Chaloner, Penny A.

Dewa, Shaliza Z.

Lopez, Gregorio

Hitchcock, Peter B.

Momblona, Francisca

Serrano, Jose L.

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Article abstract of DOI:10.1016/S0022-328X(96)06627-2

Reaction of [Ir(cod)(py)₂][PF₆] with PPh₃ or P(C₆H₄-4-F)₃ gives the bis(phosphine) derivative [Ir(cod)L₂][PF₆], but with the poorly basic phosphine P(C₆H View More

Full text of DOI:10.1016/S0022-328X(96)06627-2

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Product name:[Ir(tris(4-fluorophenyl)phosphine)2(1,5-cyclooctadiene)]PF₆

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