Carbon-Carbon Bond Formation with New Mitsunobu Reagents

DOI: 10.1016/0040-4039(95)00300-2

Source and publish data:

Tetrahedron Letters p. 2531 - 2534 (1995)

Update date:2022-08-04

Topics:

Authors:

Tsunoda, Tetsuto

Nagaku, Miwa

Nagino, Chisato

Kawamura, Yumi

Ozaki, Fumie

et al. et al.

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Article abstract of DOI:10.1016/0040-4039(95)00300-2

The efficiency of three azodicarboxylic acid derivatives and a stabilized phosphorane in the Mitsunobu type C-C bond formation was compared utilizing the reactions of three nucleophiles of different pK_a's and several alcohols of different structure types.The study established the characteristics of each reagent.The synthesis of two insect pheromone analogs was accomplished effectively using these homologation reactions.

Full text of DOI:10.1016/0040-4039(95)00300-2

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