Preparation of α-Haloacylsilane and its Use for Triethylborane-Induced Reformatsky Type Reaction

DOI: 10.1016/00404-0399(50)0985L-

Source and publish data:

Tetrahedron Letters p. 5353 - 5356 (1995)

Update date:2022-08-04

Topics:

Authors:

Horiuchi, Yoshihiro

Taniguchi, Masahiko

Oshima, Koichiro

Utimoto, Kiitiro

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Article abstract of DOI:10.1016/00404-0399(50)0985L-

Treatment of 2-halo-2-trimethylsilyloxirane with metal salts such as ZnCl2, ZnBr2, NaI, and AgBF4 gave the corresponding α-haloacylsilanes in good yields.An addition of triethylborane to haloacylsilane provided boron enolate which reacted with aldehydes t

Full text of DOI:10.1016/00404-0399(50)0985L-

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