Synthesis of Phosphinochalcogenoic Amidato Complexes of Zinc and Cadmium. The Crystal and Molecular Structure of 2>

DOI: 10.1039/DT9950002813

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2813 - 2818 (1995)

Update date:2022-08-04

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Authors:

Bochmann, Manfred

Bwembya, Gabriel C.

Hursthouse, Michael B.

Coles, Simon J.

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Article abstract of DOI:10.1039/DT9950002813

The protolysis of zinc and cadmium amides 2> with 2 equivalents of phosphinochalcogenoic amides t-Bu2P(E)NHR (E = Se or Te, R = i-Pr or C6H11) gave the complexes 2> (M = Zn or Cd).The thermally stable compounds are monomeric and sublime readily.If the protolysis reaction is carried out in a molar ratio 1 : 1, the mixed-ligand compounds > can be isolated for zinc but not for cadmium.The crystal structure of 2> has been determined.The complex possesses a distorted tetrahedral structure.The ligands are bidentate, with short <1.981(3) Angstroem> Zn-N and comparatively long <2.5375(9) Angstroem> Zn-Se bonds.

Full text of DOI:10.1039/DT9950002813

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