Platinum-mediated P=C bond cleavage in a phosphaketene: Formation and structure of the first mononuclear diphosphaureylene complex

DOI: 10.1021/om00009a004

Source and publish data:

Organometallics p. 4040 - 4042 (1995)

Update date:2022-08-03

Topics:

Authors:

David, Marie-Anne

Glueck, David S.

Yap, Glenn P. A.

Rheingold, Arnold L.

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Reactions of Mes*P=C=O (1; Mes* = 2,4,6-(t-Bu)₃C₆H₂) with (PPh₃)₂Pt(C₂H₄) (2) and (PCy₃)₂Pt (3; Cy = cyclo-C₆H₁₁) give the diphosphaur

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