Journal of the Chemical Society. Chemical communications p. 1077 - 1080 (1995)
Update date:2022-08-05
Topics:
Crossley, Maxwell J.
Hambley, Trevor W.
Mackay, Lindsey G.
Try, Andrew C.
Walton, Robin
2-Amino-5,10,15,20-tetraarylporphyrins react with formaldehyde to give good yields of the corresponding octaaryl derivatives of the Troeger's base analogue in which two porphyrins are covalently linked by a diazocine bridge; the X-ray crystal structure of the bis(tetraphenylporphyrinato)dipalladium(II) derivative 6 reveals a concave chiral cavity with two metal ion binding sites suitable for ditopic interactions with guest molecules.
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(1995)
