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Bis(diphenylphosphino)methane and its sulphide or selenide derivatives as ligands in ruthenium(II) and rhodium(III) complexes: crystal structureof [(η6C6Me6)Ru{SPPh2)2CH}]ClO4

DOI: 10.1016/0277-5387(94)00494-Y

Source and publish data:

Polyhedron p. 2239 - 2246 (1995)

Update date:2022-08-05

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Authors:

Valderrama, MauricioValderrama, Mauricio

Contreras, RaulContreras, Raul

Bascunan, ManuelBascunan, Manuel

Alegria, SergioAlegria, Sergio

Boys, DaphneBoys, Daphne

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Article abstract of DOI:10.1016/0277-5387(94)00494-Y

Reaction of complexes [(η6C6Me6)RuCl2]2 and [(η5C5Me5)RhCl2]2 with the ligands L=Ph2PCH2PPh2 (dppm) or Ph2PCH2P(Se)Ph2 in benzene solutions led to neutral complexes with the general formula [(ring)MCl2(η1L)]. The reactivity of the uncoordinated P atom of

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Full text of DOI:10.1016/0277-5387(94)00494-Y

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Product name:(C5(CH3)5)RhCl((C6H5)2PCH2P(C6H5)2)(1+)*ClO4(1-)=[(C5(CH3)5)RhCl((C6H5)2PCH2P(C6H5)2)]ClO4

Cas No:169897-75-0

169897-75-0

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