Bis(diphenylphosphino)methane and its sulphide or selenide derivatives as ligands in ruthenium(II) and rhodium(III) complexes: crystal structureof [(η6C6Me6)Ru{SPPh2)2CH}]ClO4

DOI: 10.1016/0277-5387(94)00494-Y

Source and publish data:

Polyhedron p. 2239 - 2246 (1995)

Update date:2022-08-05

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Authors:

Valderrama, Mauricio

Contreras, Raul

Bascunan, Manuel

Alegria, Sergio

Boys, Daphne

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Article abstract of DOI:10.1016/0277-5387(94)00494-Y

Reaction of complexes [(η6C6Me6)RuCl2]2 and [(η5C5Me5)RhCl2]2 with the ligands L=Ph2PCH2PPh2 (dppm) or Ph2PCH2P(Se)Ph2 in benzene solutions led to neutral complexes with the general formula [(ring)MCl2(η1L)]. The reactivity of the uncoordinated P atom of

Full text of DOI:10.1016/0277-5387(94)00494-Y

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