Enantioselective synthesis of (-)-desoxoprosopinine by radical cyclization

DOI: 10.1016/0957-4166(95)00189-V

Source and publish data:

Tetrahedron Asymmetry p. 1525 - 1526 (1995)

Update date:2022-08-04

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Authors:

Yuasa Yuasa

Ando Ando

Shibuya Shibuya

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Article abstract of DOI:10.1016/0957-4166(95)00189-V

Reaction of the aldehyde 12 with tributyrin hydride in the presence of AIBN gave a mixture of 13 as a 2:1 mixture of 8β-ol and 8α-ol. Conversion of 14, derived from 13, to (-)-desoxoprosopinine 3 was successfully achieved.

Full text of DOI:10.1016/0957-4166(95)00189-V

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