A Versatile Synthetic Method for Diiron Bridging Allenylidene Complexes (η5-C5Me5)2Fe2(μ-CO)(CO)2(μ-η1:η1-C=C=CR1R2) via Nucleophilic Addition to the Ethynediyldiiron Complex (μ-CC)5-C5Me5)(CO)2>2

DOI: 10.1039/c39950001611

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1611 - 1612 (1995)

Update date:2022-08-04

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Authors:

Terada, Masako

Masaki, Yoshiko

Tanaka, Masako

Akita, Munetaka

Moro-oka, Yoshihiko

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Article abstract of DOI:10.1039/c39950001611

Addition of an excess amount of nucleophile (alkyllithium or LiHBEt3) to the ethynediyldiiron complex (η⁵-C5Me5)(CO)2Fe-CC-Fe(η⁵-C5Me5)(CO)2 1 in portions, affords a variety of diiron bridging allenylidene complexes (η⁵-C5Me5)2Fe2(μ-CO)(CO)2(μ-C=C=CR1R2) 2 (R1, R2 = H, Me, Bu, Ph) including the parent compound 2a (R1 = R2 = H).

Full text of DOI:10.1039/c39950001611

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