A Versatile Synthetic Method for Diiron Bridging Allenylidene Complexes (η5-C5Me5)2Fe2(μ-CO)(CO)2(μ-η1:η1-C=C=CR1R2) via Nucleophilic Addition to the Ethynediyldiiron Complex (μ-CC)5-C5Me5)(CO)2>2

DOI: 10.1039/c39950001611

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1611 - 1612 (1995)

Update date:2022-08-04

Topics:

Authors:

Terada, Masako

Masaki, Yoshiko

Tanaka, Masako

Akita, Munetaka

Moro-oka, Yoshihiko

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39950001611

Addition of an excess amount of nucleophile (alkyllithium or LiHBEt3) to the ethynediyldiiron complex (η⁵-C5Me5)(CO)2Fe-CC-Fe(η⁵-C5Me5)(CO)2 1 in portions, affords a variety of diiron bridging allenylidene complexes (η⁵-C5Me5)2Fe2(μ-CO)(CO)2(μ-C=C=CR1R2) 2 (R1, R2 = H, Me, Bu, Ph) including the parent compound 2a (R1 = R2 = H).

Full text of DOI:10.1039/c39950001611

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(η(5)-C5Me5)2Fe2(μ-C=C=CH(Ph))(μ-CO)(CO)2

Cas No:169780-85-2

R&D Labs maybe for 169780-85-2

Phantom-pharma

Contact:

Address:
Chengdu Cogon Bio-tech Co., Ltd.

Contact:86-28-85171192

Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China
Sino Rarechem Labs Co.Ltd

Contact:+86-0512-62857507

Address:Boji Science Park, No1688C,Taishan road, Suzhou ,China
Lanzhou SchiffChem Co.,Ltd

Contact:86-931-8272767

Address:Room 602, No.461, Nanchang Road, Chengguan District, Lanzhou City, China PRC

Relevant to this article

Synthesis of aminomethylated calix[4] resorcinarenes

Doi:10.1016/S0040-4039(00)60145-4
(1993)
Polysulfane antitumor agents from o-benzyne. An odd-even alternation found in the stability of products o-C₆H₄S_x (x = 1-8)

Doi:10.1021/jo049418w
(2004)
Comparative evaluation of the antioxidant activity of some ortho-substituted mono- and dialkylphenols with the para-positioned hydroxymethyl group

Doi:10.1007/s11172-020-2937-x
(2020)
Tetrafluoroaryl azide as an N-Terminal capping group for click-To-dissolve diphenylalanine hydrogels

Doi:10.1039/d0ra01013h
(2020)
Diphenylpropionic acids as new AT₁ selective angiotensin II antagonists

Doi:10.1021/jm9508853
(1996)
Synthesis and cytotoxicity of water-soluble ambrosin prodrug candidates

Doi:10.1021/jm00017a025
(1995)

Article Doi