Recueil des Travaux Chimiques des Pays-Bas p. 51 - 60 (1995)
Update date:2022-08-05
Topics: Synthesis Intermediates Thiophene Chemical Synthesis Sulfonyl group Heterocyclic Allenyl sulfones
Linden, Johannes B. van der
Asten, Peter F. T. M. van
Braverman, Samuel
Zwanenburg, Binne
The synthesis of thiophenes starting from allenyl sulfones, via intermediate formation of α,β-unsaturated sulfines, is described.The allenyl sulfones were synthesized by a <2,3>-sigmatropic rearrangement of appropriately substituted prop-2-ynyl sulfinates
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