Tetrahedron Letters p. 4089 - 4092 (1995)
Update date:2022-08-05
Topics: Characterization Stereoselective synthesis Building blocks Protecting groups Isolation and Purification Retrosynthetic analysis Final steps Global Deprotection Bond Formation
Kang, Sung Ho
Lee, Sung Bae
D-(+)-Showdomycin, first isolated from Streptomyces showdoensis, has been synthesized starting from syn-2,5-disubstituted dihydrofuran 3.The key conversion was the functionalization of 2-thiophenylfuranyl group in 13 into maleic acid moiety in 12.
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Doi:10.1021/jo00128a042
(1995)Doi:10.1021/jo01019a509
(1965)Doi:10.1016/0040-4039(95)01319-D
(1995)Doi:10.1021/jo00129a026
(1995)Doi:10.1139/v02-012
(2002)Doi:10.1039/c8sc01082j
(2018)
