II. 1,3-Dipolar cycloadditions to unsaturated boronic esters. Synthesis of borylated 2-isoxazolines. Conversion of some cycloadducts to 5-hydroxy-2-isoxazolines, 5-hydroxymethyl-2-isoxazolines and isoxazoles

DOI: 10.1016/0022-328X(95)05531-S

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Journal of Organometallic Chemistry p. 229 - 236 (1995)

Update date:2022-08-05

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Authors:

Jazouli, M.

Baba, S.

Carboni, B.

Carrie, R.

Soufiaoui, M.

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Article abstract of DOI:10.1016/0022-328X(95)05531-S

A variety of borylated 2-isoxazolines was prepared by 1,3-cycloaddition reactions of nitrile oxides to vinyl- and allylboronic esters.The influence of substituents on the reactivity, the regio- and stereoselectivity was examined and some examples of cycloadduct oxidation were described.Keywords: Boron; 2-Isoxazolines; Synthesis; Cycloaddition; Isoxazoles

Full text of DOI:10.1016/0022-328X(95)05531-S

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