Reaction of alkyne having hydroxyphenyl group with Mo(CO)6

DOI: 10.1246/cl.1995.627

Source and publish data:

Chemistry Letters p. 627 - 628 (1995)

Update date:2022-08-05

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Authors:

Kaneta, Naotake

Hirai, Tomoe

Mori, Miwako

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Article abstract of DOI:10.1246/cl.1995.627

The reaction of m- and p-hydroxyphenylpropyne, 1a and 1b, with Mo(CO)6 (5 mol percent) affords metathesis products, 2a and 2b, in 78percent and 14percent (conversion yield, 78percent) yields,respectively.However, o-hydroxyphenylpropyne 1f gave trimerization product 4 in 65percent yield.

Full text of DOI:10.1246/cl.1995.627

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