Reaction of alkyne having hydroxyphenyl group with Mo(CO)6

DOI: 10.1246/cl.1995.627

Source and publish data:

Chemistry Letters p. 627 - 628 (1995)

Update date:2022-08-05

Topics:

Authors:

Kaneta, Naotake

Hirai, Tomoe

Mori, Miwako

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1995.627

The reaction of m- and p-hydroxyphenylpropyne, 1a and 1b, with Mo(CO)6 (5 mol percent) affords metathesis products, 2a and 2b, in 78percent and 14percent (conversion yield, 78percent) yields,respectively.However, o-hydroxyphenylpropyne 1f gave trimerization product 4 in 65percent yield.

Full text of DOI:10.1246/cl.1995.627

Products guided by the article

Product name:Acetic acid 10-acetoxy-dec-5-ynyl ester

Cas No:170651-26-0

R&D Labs maybe for 170651-26-0

Chengdu Chengnuo New-Tech Co., Ltd

Contact:0086-028-85749078

Address:4 Jiuyang road,Jiulong industrial port,Chengdu, China
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Changsha Huajing Powdery Material Technological Co., Ltd.

Contact:86-731-88879686

Address:Building 2, West Garden, Main Campus of Central South University, Changsha, Hunan Province, China
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
Jiangsu Allyrise Pharmaceutical Co., Ltd.(expird)

Contact:+86-523-86818997

Address:Taizhou,Jiangsu Province,CHINA

Relevant to this article

Application of Polyphosphoric Acid-Mediated Acyl Migration for Regiospecific Synthesis of Diverse 2-Acylpyrroles from Chalcones

Doi:10.1002/jhet.3494
(2019)
Heterogeneous Catalysis with Basic Compounds to Achieve the Synthesis and C-N Cleavage of Azetidin-2-ones under Microwave Irradiation

Doi:10.1055/s-0037-1611851
(2019)
Synthesis of the water-soluble adenosine A₁ receptor antagonist FR166124 through a novel sequential Horner-Emmons/isomerization reaction

Doi:10.1016/S0040-4020(99)00590-6
(1999)
Molecular diversity via a convertible isocyanide in the Ugi four-component condensation

Doi:10.1021/ja00134a044
(1995)
Silica gel-catalysed addition of methyl nitroacetate to 1,2:3,4-di-O-isopropylidene-α-D-galacto-hexodialdo-1,5-pyranose and 2,3-O-isopropylidene-D-glyceraldehyde. Crystal structure of methyl 7-acetamido-7-deoxy-1,2:3,4-di-O-isopropylidene-L-threo-α-D-galacto-octopyranuronate

Doi:10.1016/0008-6215(95)00027-Q
(1995)
Liquid crystalline compounds based on 1,4-disubstituted but-1-YNE

Doi:10.1080/10587259508038692
(1995)

Article Doi