Stereospecific α-alkoxystannane couplings with acyl chlorides: Total synthesis of (+)-goniofufurone

DOI: 10.1016/S0040-4039(00)61436-3

Source and publish data:

Tetrahedron Letters p. 8007 - 8010 (1993)

Update date:2022-08-02

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Authors:

Ye, Jianhua

Bhatt, Rama K.

Falck Falck

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Article abstract of DOI:10.1016/S0040-4039(00)61436-3

Stereospecific C-glycoside formation via Pd/Cu mediated coupling of PhCOCl with cyclic α-alkoxystannane 6, derived from D-glucurono-6,3-lactone, was the key transformation in a concise total synthesis of the anticancer agent (+)-goniofufurone.

Full text of DOI:10.1016/S0040-4039(00)61436-3

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Product name:(+)-1,2-O-Isopropylidene-5-O-(phenoxythiocarbonyl)-α-D-glucurono-6,3-lactone

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