Tetrahedron Letters p. 5595 - 5598 (1995)
Update date:2022-08-03
Topics:
Urabe, Hirokazu
Yoshikawa, Kaoru
Sato, Fumie
The (η5-indenyl)2(η3-2-alkyl-1-methylallyl)Ti complex 10, successfully generated from (η5-indenyl)2TiCl2 8, 2-alkylbutadiene, and i-PrMgCl, reached with carbon dioxide or RCHO (R = Ph, ET, i-Pr, or t-Bu) to give the corresponding optically active β,γ-unsaturated carboxylic acid 11 or threohomoallyl alcohols 12-15 with high enantiomeric purities of up to 96%.
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Doi:10.1002/hlca.19620450117
(1962)Doi:10.1021/ja00136a008
(1995)Doi:10.1021/ja963968x
(1997)Doi:10.1016/j.bmcl.2006.11.067
(2007)Doi:10.1055/s-1995-4034
(1995)Doi:10.1016/0040-4020(95)00704-C
(1995)
