Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro( phenyl) silane

DOI: 10.1016/0022-328X(95)00311-D

Source and publish data:

Journal of Organometallic Chemistry p. 167 - 172 (1995)

Update date:2022-09-26

Topics:

Authors:

Ohmura, Hideaki

Matsuhashi, Hayao

Tanaka, Makoto

Kuroboshi, Manabu

Hiyama, Tamejiro

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(95)00311-D

A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.Keywords: Chirality; Fluorine; Silane; Ferrocene; Silicon; Palladium

Full text of DOI:10.1016/0022-328X(95)00311-D

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