Catalytic asymmetric hydrosilylation of 1,3-dienes with difluoro( phenyl) silane

DOI: 10.1016/0022-328X(95)00311-D

Source and publish data:

Journal of Organometallic Chemistry p. 167 - 172 (1995)

Update date:2022-09-26

Topics:

Authors:

Ohmura, Hideaki

Matsuhashi, Hayao

Tanaka, Makoto

Kuroboshi, Manabu

Hiyama, Tamejiro

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(95)00311-D

A palladium complex with an optically active ligand catalyzes asymmetric hydrosilylation of 1,3-dienes using difluoro(phenyl)silane to give optically active allyl difluoro(phenyl)silanes in good enantiomeric excess.Keywords: Chirality; Fluorine; Silane; Ferrocene; Silicon; Palladium

Full text of DOI:10.1016/0022-328X(95)00311-D

Products guided by the article

Product name:Silane, 2-cyclohexen-1-yldifluorophenyl-, (S)-

Cas No:171000-89-8

R&D Labs maybe for 171000-89-8

Qingzhou Baibang import and export co.,Ltd

Contact:+86-536-3265899

Address:No.338, Tuoshan Road
Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Tianjin Ingenochem Technology Co.,Ltd

Contact:+86-22-23677060

Address:Hitech Green Industry Park K2-9-602, Nankai district
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
Nanjing Samwon International Limited

Contact:+86-25-84873444

Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,

Relevant to this article

Chiral sulfoxides in asymmetric synthesis: Enantioselective synthesis of the lactonic moiety of (+)-compactin and (+)-mevinolin. Application to a compactin analogue

Doi:10.1021/jo00129a018
(1995)
Platinum catalyzed H-D exchange reaction of various aromatic compounds under hydrothermal condition

Doi:10.3987/COM-05-S(T)36
(2006)
Diastereoselective epoxidation of alpha'-alkoxy substituted cyclohexenyl ketones

Doi:10.1016/00404-0399(50)1367-Q
(1995)
Synthesis and Selective Deprotection of the Penta-N-Protected Polyamine 1,16-Diamino-4,8,13-triazahexadecane

Doi:10.1016/0040-4020(95)00811-L
(1995)
Direct synthesis of anthracenes from o-tolualdehydes and aryl iodides through Pd(II)-Catalyzed sp³ C–H arylation and electrophilic aromatic cyclization

Doi:10.1016/j.tet.2018.03.006
(2018)
Doi:10.1021/jo01273a002
(1968)

Article Doi