Synthesis and Selective Deprotection of the Penta-N-Protected Polyamine 1,16-Diamino-4,8,13-triazahexadecane

DOI: 10.1016/0040-4020(95)00811-L

Source and publish data:

Tetrahedron p. 12573 - 12582 (1995)

Update date:2022-09-26

Topics:

Authors:

Goulaouic-Dubois, Catherine

Guggisberg, Armin

Hesse, Manfred

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Article abstract of DOI:10.1016/0040-4020(95)00811-L

The synthesis of the penta-N-protected polyamine thermopentamine -carbamate>, containing five different N-protecting groups is described.These protecting groups include tert-butoxycarbonyl, benzyl, trifluoroacetyl, diallyl, and pyridine-2-sulfonyl.In spite of the syntheses of specific polyamine derivatives the selective removal of each of these groups has been investigated.

Full text of DOI:10.1016/0040-4020(95)00811-L

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