Journal of the Chemical Society. Chemical communications p. 1139 - 1142 (1994)
Update date:2022-07-30
Topics:
Cole, Andrew G.
Gani, David
A high energy conformation, in which the adenine moiety of adenosine 2'-phosphate occupies a C-1'-axial ribofuranosyl position, is stabilised through the chelation of a second (additional) Mg2+ ion by the 2'- and furanose ring O-atoms; with inositol 1-phosphate as the substrate, the 1- and 6-O-atoms chelate the second Mg2+ ion and for both substrates a different (buried) Mg2+ ion interacts directly with the phosphate moiety.
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