Template-directed intramolecular C-glycosidation. Total synthesis of 2,3-dideoxy-D-manno-2-octulopyranosonic acid

DOI: 10.1016/0040-4039(95)01104-P

Source and publish data:

Tetrahedron Letters p. 5815 - 5818 (1995)

Update date:2022-08-04

Topics:

Authors:

Craig, Donald

Pennington, Mark W.

Warner, Peter

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Article abstract of DOI:10.1016/0040-4039(95)01104-P

The total synthesis of the KDO-inhibitor 2,3-dideoxy-D-manno-2-octulopyranosonic acid (2-deoxy-KDO) starting from TBDPS-protected (S)-glycidol and 3,3-dimethoxy-1-(phenylsulfonyl)-propane is described. The key steps are silver(I) trifluoromethylsulfonate-

Full text of DOI:10.1016/0040-4039(95)01104-P

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