Neutral hexacoordinate silicon complexes. Synthesis, structure, and stereodynamics: Evidence for two nondissociative ligand-exchange mechanisms

Article abstract of DOI:10.1021/ja00151a015

Novel hexacoordinate silicon compounds 1-4 with two identical bidentate ligands, respectively, are readily prepared in high yields from the reaction of XSiCl₃ (X = H, Me, Ph, Cl) with the ο-trimethylsilyl derivatives of N,N-dimethyl carbohydraz