Characterization and X-Ray Structure of the Adduct Formed Between Triphenyltin Chloride and Dicyclohexylphosphinyl-N-methyl(thioformamide): Ph3SnCl

Article abstract of DOI:10.1071/CH9951659

The reaction of Ph3SnCl and Cy2P(O)C(S)N(H)Me yields the air-stable adduct Ph3SnCl which features a trigonal bipyramidal tin atom geometry with a chlorine atom and an oxygen atom derived from a monodentate phosphinyl(thioformamide) ligand, occupying the axial positions.The pale-yellow crystals are monoclinic, space group P2₁/c with unit cell dimensions a 10.050(1), b 16.501(1), c 19.273(1) Angstroem, β 102.12(1) deg, Z 4; the structure was refined to final R 0.031 by using 5384 reflections.