Synthesis, Properties and Molecular Structures of Iron(III), Cobalt(II), Nickel(II), Copper(II), Copper(I) and Zinc(II) Complexes with N,N-Bis(pyrazol-1-ylmethyl)benzylamine

DOI: 10.1039/DT9950003503

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3503 - 3510 (1995)

Update date:2022-08-03

Topics:

Authors:

Sheu, Shiann-Cherng

Tien, Mong-Jong

Cheng, Ming-Chun

Ho, Tong-Ing

Peng, Shie-Ming

Lin, Yuan-Chuan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950003503

A newly prepared ligand, N,N-bis(pyrazol-1-ylmethyl)benzylamine (L) reacted with metal ions to form , , (M = Co(II), Cu(II) or Zn(II), X = Cl(-), Br(-) or NCS(-)) and <(CuLI)2>.The crystallographically determined structures of and reveal the co-ordination sphere of cobalt(II) to be intermediate between distorted tetrahedral and trigonal bipyramidal.In the co-ordination sphere of nickel(II) ion is distorted octahedral while that of copper(II) in is distorted square pyramidal.The complex <(CuLI)2> displays distorted tetrahedral geometry around copper(I), and shows distorted tetrahedral geometry around zinc(II).

Full text of DOI:10.1039/DT9950003503

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Co(N,N-bis(pyrazol-1-ylmethyl)benzylamine)(NCS)2]

Cas No:171672-22-3

R&D Labs maybe for 171672-22-3

NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Nanjing Norris Pharm Technology Co., Ltd.

Contact:+86-13901585132

Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
Synchem Pharma Co.,Ltd(expird)

Contact:+0086-21-61984905-1

Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China

Relevant to this article

Total synthesis of an acaricide, gualamycin

Doi:10.1016/00404-0399(50)1360T-
(1995)
Synthesis of (Me3SiCH2Sb)n and reactions with ditellurides: crystal structure of

Doi:10.1016/0022-328X(95)05621-U
(1995)
Doi:10.1007/BF00899160
(1949)
Synthesis, transformation, and general pharmacologic activity in 1,4-benzodiazepine-3,5-diones.

Doi:10.1021/jm00294a028
(1971)
A versatile method for the preparation of substituted 1,2,3,4-tetrahydroquinolines

Doi:10.1021/jo00128a041
(1995)
Semipermanent p-nitrobenzyloxycarbonyl (pNZ) protection of Orn and Lys side chains: Prevention of undesired α-Fmoc removal and application to the synthesis of cyclic peptides

Doi:10.1016/j.tetlet.2005.09.043
(2005)

Article Doi