Synthesis, Properties and Molecular Structures of Iron(III), Cobalt(II), Nickel(II), Copper(II), Copper(I) and Zinc(II) Complexes with N,N-Bis(pyrazol-1-ylmethyl)benzylamine

DOI: 10.1039/DT9950003503

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3503 - 3510 (1995)

Update date:2022-08-03

Topics:

Authors:

Sheu, Shiann-Cherng

Tien, Mong-Jong

Cheng, Ming-Chun

Ho, Tong-Ing

Peng, Shie-Ming

Lin, Yuan-Chuan

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Article abstract of DOI:10.1039/DT9950003503

A newly prepared ligand, N,N-bis(pyrazol-1-ylmethyl)benzylamine (L) reacted with metal ions to form , , (M = Co(II), Cu(II) or Zn(II), X = Cl(-), Br(-) or NCS(-)) and <(CuLI)2>.The crystallographically determined structures of and reveal the co-ordination sphere of cobalt(II) to be intermediate between distorted tetrahedral and trigonal bipyramidal.In the co-ordination sphere of nickel(II) ion is distorted octahedral while that of copper(II) in is distorted square pyramidal.The complex <(CuLI)2> displays distorted tetrahedral geometry around copper(I), and shows distorted tetrahedral geometry around zinc(II).

Full text of DOI:10.1039/DT9950003503

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