A Stereocontrolled Route to Both Enantiomers of the Necine Base Dihydroxyheliotridane via Intramolecular 1,3-Dipolar Addition Using the Same Chiral Precursor

DOI: 10.1039/c39950002291

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Journal of the Chemical Society. Chemical communications p. 2291 - 2292 (1995)

Update date:2022-08-03

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Authors:

Hashimura, Kazuya

Tomita, Shun'ichi

Hiroya, Kou

Ogasawara, Kunio

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Article abstract of DOI:10.1039/c39950002291

Diastereofacial selectivity in an enantiospecific intramolecular 1,3-dipolar addition is controlled by adjusting the size of the tether between the dipole and the dipolarophile to give 2,3-disubstituted pyrrolidines enantiomeric with respect to the newly

Full text of DOI:10.1039/c39950002291

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