Borole derivatives XXI. 2,5-Diphenyl-2,5-dihydro-1H-boroles; structures of tert-butyl-2,5-diphenyl-2,5-dihydro-1H-borole and of bis(tmeda)lithium 2,5-diphenyl-2,5-dihydro-1H-borolediide

DOI: 10.1016/0022-328X(95)05818-A

Source and publish data:

Journal of Organometallic Chemistry p. 67 - 74 (1995)

Update date:2022-08-04

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Authors:

Herberich, Gerhard E.

Wagner, Trixie

Marx, Hans-W.

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Article abstract of DOI:10.1016/0022-328X(95)05818-A

The magnezium reagent Mg(C4H4Ph2)(THF)3 derived from (E,E)-1,4-diphenyl-1,3-butadiene reacts with boron dihalides BCl2(NR2) (R=Me, Et, i-Pr) and t-BuBF2 to give 2,5-dihydro-2,5-diphenyl-1H-boroles 2,5-Ph2C4H4BNR2 (1a-1c) and 2,5-Ph2C4H4Bt-Bu (1d) as mixtu

Full text of DOI:10.1016/0022-328X(95)05818-A

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