Synthesis of a C14′, 15′ dihydro derivative of the south hexacyclic steroid unit of cephalostatin 1. Part I: Regiospecific Rh[II]-mediated intermolecular oxygen alkylation of a primary neopentyl alcohol

DOI: 10.1016/0040-4039(95)01804-Q

Source and publish data:

Tetrahedron Letters p. 8347 - 8350 (1995)

Update date:2022-07-31

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Authors:

Bhandaru, Sudhakar

Fuchs Fuchs

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Article abstract of DOI:10.1016/0040-4039(95)01804-Q

Hecogenin acetate 5 was converted to an intermediate suitable for the construction of a C_{14′, 15′} dihydro derivative of the "South" hexacyclic spiroketal of cephalostatin 1 1. The key transformations include: (i) proximal functionalization of t

Full text of DOI:10.1016/0040-4039(95)01804-Q

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