Redox Tuning of the Dimolybdenum Compounds at the Ligand Periphery: A Direct Correlation with the Hammett Constant of the Substituents

DOI: 10.1039/c39950002257

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2257 - 2258 (1995)

Update date:2022-08-03

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Authors:

Lin, Chun

Protasiewicz, John D.

Smith, Eugene T.

Ren, Tong

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Article abstract of DOI:10.1039/c39950002257

Oxidation potentials of (Ar = aryl), a direct measure of the HOMO (δ orbital) energy, correlate with the Hammett constant of aryl substituents, while both structural and spectroscopic data indicate that the valence structure around the dinuclear core is unperturbed.

Full text of DOI:10.1039/c39950002257

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