Mono- and binuclear rhodium complexes of a chiral 1,1-diphosphine. Syntheses and crystal structures

DOI: 10.1021/om00011a006

Source and publish data:

Organometallics p. 4983 - 4985 (1995)

Update date:2022-08-04

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Authors:

Marinetti, Angela

Le Menn, Claude

Ricard, Louis

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Article abstract of DOI:10.1021/om00011a006

The homochiral diphosphine 3, bearing PPh₂ and menthylphosphetane moieties, has been prepared from the phosphetane oxide 1 through a stereoselective phosphorylation reaction. Monometallic and bimetallic A-frame rhodium complexes of 3 have been synthesized and characterized by X-ray diffraction.

Full text of DOI:10.1021/om00011a006

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Product name:Rh₂(Cl)(CO)2((C₆H₅)2PC₃H(CH₃)4PC₆H₉(CH₃)CH(CH₃)2)2⁽¹⁺⁾*Cl^(1-)=[Rh₂(Cl)(CO)2((C₆H₅)2PC₃H(CH₃)4PC₆H₉(CH₃)CH(CH₃)2)2]Cl

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