Asymmetric Ring Cleavage Reaction Based on Crossed Aldol Condensation

DOI: 10.1016/0040-4039(95)01504-B

Source and publish data:

Tetrahedron Letters p. 7259 - 7262 (1995)

Update date:2022-07-29

Topics:

Authors:

Suemune, Hiroshi

Yoshida, Osamu

Uchida, Jun

Nomura, Yukiko

Tanaka, Masakazu

Sakai, Kiyoshi

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Article abstract of DOI:10.1016/0040-4039(95)01504-B

Ring cleavage reaction based on crossed aldol condensation of carbobicyclic ketones with benzaldehyde under acetalization conditions (BF3*Et2O/ethylene glycol) was studied.By using optically active 1,2-diols instead of ethylene glycol, an asymmetric version of this reaction could be developed for the first time.

Full text of DOI:10.1016/0040-4039(95)01504-B

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