The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds with sulfenate esters

Article abstract of DOI:10.1080/10426509708044221

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, Ar_nP(OCH₂CF₃)_3-n with arylsulfenate esters, ArSOCH₂CF₃, are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step mechanism involving arylthiophosphoranes as intermediates.

Full text of DOI:10.1080/10426509708044221

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Phosphorus, Sulfur, and Silicon and the
Related Elements
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THE KINETICS AND MECHANISM OF
THE REACTION OF TRICOORDINATE
PHOSPHORUS COMPOUNDS WITH
SULFENATE ESTERS
C. Dennis Hall a , Bruce R. Tweedy a & Nicholas Lowther a
a Department of Chemistry, King's College London, Strand, London,
WC2R 2LS, UK
Published online: 04 Oct 2006.
To cite this article: C. Dennis Hall , Bruce R. Tweedy & Nicholas Lowther (1997) THE KINETICS
AND MECHANISM OF THE REACTION OF TRICOORDINATE PHOSPHORUS COMPOUNDS WITH
SULFENATE ESTERS, Phosphorus, Sulfur, and Silicon and the Related Elements, 123:1, 341-358, DOI:
10.1080/10426509708044221
To link to this article: http://dx.doi.org/10.1080/10426509708044221
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