Exchange of Organoimido Groups at a Mononuclear Titanium Centre and a Crystallographic Evaluation of the Relative Structural Influences of the NBut, NC6H4Me-4 and NC6H4NO2-4 Ligands

DOI: 10.1039/DT9950003743

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3743 - 3746 (1995)

Update date:2022-08-04

Topics:

Authors:

Collier, Philip E.

Dunn, Simon C.

Mountford, Philip

Shishkin, Oleg V.

Swallow, Daniel

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950003743

The tert-butylimido complex t)Cl2(py)3> 1a (py = pyridine) undergoes exchange reactions of the NBu^t ligand with arylamines RNH2 to form the arylimido derivatives (R = C6H4Me-4 1b, C6H4NO2-4 1c or C6H3Me2-2,6 1d); comparison of the crystal structures of 1a-1c gave a direct evaluation of N-substituent effects in d⁰, six-co-ordinated organoimido complexes.

Full text of DOI:10.1039/DT9950003743

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:trans,mer-[Ti(4-nitrophenylimide)Cl₂(pyridine)3]

Cas No:172481-13-9

R&D Labs maybe for 172481-13-9

Taizhou KEDE Chemical.Co.,Ltd.

Contact:86-576-84613060

Address:Jiangkou Chemical Zoon
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan
Jiangsu Cale New Material Co.ltd

Contact:+86-515-88334667/88203550

Address:Zhongshan 3rd Road, Coastal Chemical Industry Park, Yancheng, Jiangsu, China
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone

Relevant to this article

Stereospecific synthesis of novel 1,3-thiazolidin-2-yl analogues of pseudouridine

Doi:10.1248/cpb.43.1601
(1995)
Reactions of triterpenoid ketones with sulfur and morpholine under the conditions of Willgerodt-Kindler reaction

Doi:10.1135/cccc19860118
(1986)
Syntheses and Structures of the Complexes cis-[M(C₆F₅)₂(N-X)] (M = Pd, Pt; N-X = 2-Iodoaniline, 2-Benzoylpyridine) Containing N-X Acting as a Didentate Chelating Ligand and Displaying I→M or O→M Interactions

Doi:10.1021/ic950283+
(1996)
Synthesis of 10(S)-hydroxyeicosatetraenoic acid: A novel cytochrome P-450 metabolite of arachidonic acid

Doi:10.1021/jo951061w
(1996)
Catenated group 14 compounds. Synthesis, structural and spectral characterization, and chemistry of the chains Me₃CSiMe₂GeMe₂SnR₃ (R = Me, Ph)

Doi:10.1021/om950752f
(1996)
1′-(diphenylphosphino)ferrocenecarboxylic acid and its P-oxide and methyl ester: Synthesis, characterization, crystal structure, and electrochemistry

Doi:10.1021/om950528q
(1996)

Article Doi