Exchange of Organoimido Groups at a Mononuclear Titanium Centre and a Crystallographic Evaluation of the Relative Structural Influences of the NBut, NC6H4Me-4 and NC6H4NO2-4 Ligands

DOI: 10.1039/DT9950003743

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3743 - 3746 (1995)

Update date:2022-08-04

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Authors:

Collier, Philip E.

Dunn, Simon C.

Mountford, Philip

Shishkin, Oleg V.

Swallow, Daniel

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Article abstract of DOI:10.1039/DT9950003743

The tert-butylimido complex t)Cl2(py)3> 1a (py = pyridine) undergoes exchange reactions of the NBu^t ligand with arylamines RNH2 to form the arylimido derivatives (R = C6H4Me-4 1b, C6H4NO2-4 1c or C6H3Me2-2,6 1d); comparison of the crystal structures of 1a-1c gave a direct evaluation of N-substituent effects in d⁰, six-co-ordinated organoimido complexes.

Full text of DOI:10.1039/DT9950003743

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