Preparation Involving a C4-C3 Ring Contraction in the Key Step of a Novel Cyclopropane Carbocyclic Nucleoside

DOI: 10.1016/0040-4039(95)01536-1

Source and publish data:

Tetrahedron Letters p. 7441 - 7444 (1995)

Update date:2022-07-29

Topics: Preparation Experimental terms Key step

Authors:

Mevellec, Laurence

Huet, Francois

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Article abstract of DOI:10.1016/0040-4039(95)01536-1

Cis-3,4-bis(benzyloxymethyl)cyclobut-1-ene 1 mainly led to bromohydrin 5 with a cis relationship between bromine and the benzyloxymethyl groups.The stereospecific ring contraction of 5 afforded aldehyde 7 which could be converted into the nucleoside analo

Full text of DOI:10.1016/0040-4039(95)01536-1

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