Tetrahedron Letters p. 8287 - 8290 (1995)
Update date:2022-07-31
Topics:
Estevez, Juan C.
Long, Daniel D.
Wormald, Mark R.
Dwek, Raymond A.
Fleet, George W. J.
The first synthesis of a spirodiketopiperazine at the anomeric carbon of a pyranose sugar is described; an N-acylated bicyclic amino [2.2.2.] lactone provides access to a new class of glycopeptide analogues of pyranoses and determines the anomeric configuration of the spirodiketopiperazine. The mannopyranose may be equilibrated to the more stable furanose form.
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(2004)Doi:10.1021/acs.orglett.7b03469
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(1995)
