Tetrahedron Letters p. 8941 - 8944 (1995)
Update date:2022-07-31
Topics:
Lu, Qingyi
Bovonsombat, Pakorn
Agosta, William C.
Irradiation of 1 and its methyl derivative 10a (λ>280 nm) in methanol leads to photohydrolysis of the nitrile group and formation of the related ketal amides 3 and 11a, respectively.Similar treatment of the dimethyl derivative 10b and of the parent nitrile 13 fails to yield corresponding products of hydrolysis.A mechanism is proposed for these novel hydrolyses.
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Doi:10.1039/P29960000789
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