Journal of the American Chemical Society p. 12712 - 12720 (1995)
Update date:2022-08-02
Topics:
Maier, Günther
Pacl, Harald
Reisenauer, Hans Peter
Meudt, Andreas
Janoschek, Rudolf
Matrix-isolated 1-silacyclopropenylidene (7) has been generated by pulsed flash pyrolysis of 2-ethynyl-1,1,1-trimethyldisilane (4). By subsequent photolysis 7 can be isomerized into ethynylsilanediyl (5), vinylidene-silanediyl (8), and silacyclopropyne (9
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