Aminolysis of O-(2,4-dinitrophenyl)-p-p′-disubstituted benzophenone oximes in benzene: Evidence for Hirst's mechanism

Article abstract of DOI:10.1002/(SICI)1099-1395(199611)9:11<770::AID-POC846>3.0.CO;2-5

The reactions of O-(2,4-dinitropnenyl)-substituted p,p′-dimethoxybenzophenone oxime, p,p′-fluorobenzophenone oxime and p,p×-dichlorobenzophenone oxime with pyrrolidine and piperidine in benzene were found to be third order in amine, with no uncatalytic ro