Generation and subsequent cycloaddition chemistry of α-amino isobenzofurans formed by cationic cyclization

DOI: 10.1016/0040-4039(95)02013-F

Source and publish data:

Tetrahedron Letters p. 9285 - 9288 (1995)

Update date:2022-08-03

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Authors:

Kappe Kappe

Oliver Kappe

Cochran Cochran

Cochran, John E.

Padwa Padwa

Padwa, Albert

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Article abstract of DOI:10.1016/0040-4039(95)02013-F

The α-thiocarbocation generated from the Pummerer reaction of an o-amido substituted sulfoxide is intercepted by the adjacent carbonyl group to produce an α-amino isobenzofuran as a transient intermediate which undergoes a subsequent Diels-Alder cycloaddi

Full text of DOI:10.1016/0040-4039(95)02013-F

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