Tetrahedron p. 233 - 244 (1996)
Update date:2022-08-03
Topics:
Sakai, Takashi
Yan, Fengyang
Kashino, Setsuo
Uneyama, Kenji
Enantiomerically enriched 3,3,3-trifluoroalanine (1) (up to 62 % ee) has been synthesized by the asymmetric reduction of 2-(N-arylimino)-3,3,3-trifluoropropanoic acid esters with a chiral oxazaborolidne catalyst and subsequent oxidative removal of N-aroma
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