Tetrahedron Asymmetry p. 1649 - 1658 (1996)
Update date:2022-09-26
Topics:
Fukazawa, Tetuya
Shimoji, Yasuo
Hashimoto, Toshihiko
Enantiomerically pure (R)-2-cyclohexen-1-ol 5 was prepared via lipase- catalyzed enantioselective transesterification of 2-substituted cyclohexanol, and stereospecifically converted to (-)-(2-cyclohexenyl)acetic acid 4. Enantiomerically pure aminoisoquinocarbazole 1 (RS-2135) was synthesized stereoselectively from 4, using an intramolecular Diels-Alder reaction and Curtius rearrangement.
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Doi:10.1021/jo9518415
(1996)Doi:10.3390/molecules21081057
(2016)Doi:10.1021/jo952127q
(1996)Doi:10.1016/0960-894X(96)00050-9
(1996)Doi:10.1021/acs.orglett.5b03535
(2016)Doi:10.1039/CC9960000167
(1996)
