Tetrahedron Asymmetry p. 1 - 4 (1996)
Update date:2022-08-04
Topics:
Palmisano, Giovanni
Annunziata, Rita
Papeo, Gianluca
Sisti, Massimo
A novel non-biomimetic synthesis of horsfiline has been developed. The key pyrrolidine forming reaction is the 1,3-dipolar cycloaddition of the thermally generated N-methylazomethine ylide to a suitable 3-akylidene-indolin-2(3H)one. The same strategy was also applied to the synthesis of pure (R)-(-)-enantiomer.
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Doi:10.1021/om9508389
(1996)Doi:10.1016/0040-4039(95)02171-X
(1996)Doi:10.1016/0040-4039(95)02258-9
(1996)Doi:10.1016/0957-4166(95)00441-6
(1996)Doi:10.1021/jo951344o
(1996)Doi:10.1002/jsfa.2740181003
(1967)
