From Dichlorocyclopropanes to Furans and Cyclopentadienes via Vinylcarbenes

DOI: 10.1002/hlca.19880710707

Source and publish data:

Helvetica Chimica Acta p. 1630 - 1637 (1988)

Update date:2022-08-03

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Authors:

Mueller, Paul

Pautex, Nicole

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Article abstract of DOI:10.1002/hlca.19880710707

Base-induced elimination of dichlorocarbene adducts 2 to 9-alkoxyphenanthrenes 1 leads to furans 6, presumably via cyclopropenes 3 which undergo rearrangement to vinylcarbenes 4 and C-H insertion.By the same sequence, the 9-substituted alkylphenanthrene a

Full text of DOI:10.1002/hlca.19880710707

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