Cycloaromatization of enediyne model compounds via a reaction cascade triggered by hydrolysis of the α-alkynylmalonates

DOI: 10.1016/0040-4039(95)02285-6

Source and publish data:

Tetrahedron Letters p. 865 - 868 (1996)

Update date:2022-08-05

Topics:

Authors:

Shibuya, Masayuki

Wakayama, Masakazu

Naoe, Yoshimitsu

Kawakami, Tadaaki

Ishigaki, Katsuya

Nemoto, Hisao

Shimizu, Hisashi

Nagao, Yoshimitsu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)02285-6

Diethyl α-methoxy-α-alkynylmalotate derivatives of cis-enediynes were synthesized and they produced toluenebiradicals via the reaction cascade triggered by ester hydrolysis. Deuterium labeling studies suggested that the reaction involved the self quenchin

Full text of DOI:10.1016/0040-4039(95)02285-6

Products guided by the article

Product name:7-Methoxymethoxy-4-phenyl-hepta-1,5-diyn-4-ol

Cas No:175025-38-4

R&D Labs maybe for 175025-38-4

Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
Jiaxing Trustworthy Import And Export Co.,Ltd

Contact:+86-573-82030555

Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
Beijing Chemdow Co., Ltd

website:http://www.chemdow.com

Contact:0086-10-82435335

Address:Room 401,Unit 3,4th Floor,Shangdijiayuan,Shangdi East Road, Haidian District,Beijing
Wuxi Olite Chemical Co., Ltd.

Contact:86-510-82853889

Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
Xian Changyue Biological Technology Co., Ltd.

website:https://www.xachangyue.com/

Contact:+86-029-88211911

Address:Keji Road NO.70

Relevant to this article

CO₂ activation. 7. Formation of the catalytically active intermediate in the hydrogenation of carbon dioxide to formic acid using the [{(COD)Rh(μ-H)}₄]/ Ph₂P(CH₂)₄PPh₂ catalyst: First direct observation of hydride migration from rhodium to coordinated 1,5-cyclooctadiene

Doi:10.1021/om950913f
(1996)
Catalytic etherification of N-protected tris(hydroxymethyl)aminomethane for the synthesis of ligands with C₃ symmetry

Doi:10.1016/j.tetlet.2006.01.026
(2006)
Synthesis of new trisulfonated calix[4]arenes functionalized at the upper rim, and their complexation with the trimethyllysine epigenetic mark

Doi:10.1021/ol300243b
(2012)
Dehalogenation of vicinal dihalo compounds by 1,1′-bis(trimethylsilyl)-1: H,1′ H-4,4′-bipyridinylidene for giving alkenes and alkynes in a salt-free manner

Doi:10.1039/c7cc07377a
(2017)
A convenient synthesis of dengibsin

Doi:10.1021/jo9601369
(1996)
Doi:10.1021/ja01126a015
(1952)

Article Doi