Cycloaromatization of enediyne model compounds via a reaction cascade triggered by hydrolysis of the α-alkynylmalonates

DOI: 10.1016/0040-4039(95)02285-6

Source and publish data:

Tetrahedron Letters p. 865 - 868 (1996)

Update date:2022-08-05

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Authors:

Shibuya, Masayuki

Wakayama, Masakazu

Naoe, Yoshimitsu

Kawakami, Tadaaki

Ishigaki, Katsuya

Nemoto, Hisao

Shimizu, Hisashi

Nagao, Yoshimitsu

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Article abstract of DOI:10.1016/0040-4039(95)02285-6

Diethyl α-methoxy-α-alkynylmalotate derivatives of cis-enediynes were synthesized and they produced toluenebiradicals via the reaction cascade triggered by ester hydrolysis. Deuterium labeling studies suggested that the reaction involved the self quenchin

Full text of DOI:10.1016/0040-4039(95)02285-6

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