Cyclenphosphine sulfide: Fluxional behaviour and ambident reactivity

DOI: 10.1016/0040-4020(96)00017-8

Source and publish data:

Tetrahedron p. 2995 - 3004 (1996)

Update date:2022-08-03

Topics:

Authors:

Oget Oget

Chuburu Chuburu

Yaouanc Yaouanc

Handel Handel

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(96)00017-8

The cyclenphosphine sulfide is prepared by reaction of molecular sulfur on cyclenphosphorane, obtained by transaminating hexamethylphosphorous triamide with 1,4,7,10-tetraazacyclododecane (cyclen). The fluxional behaviour of this compound is characterized by NMR ¹³C and ³¹P spectroscopy. Treatment of the titled compound by n-BuLi, followed by reaction with various electrophiles leads to either N- or S-alkylation according to the nature of the reactant.

Full text of DOI:10.1016/0040-4020(96)00017-8

Products guided by the article

Product name:N-benzoylcyclenphosphine sulfide

Cas No:175726-57-5

R&D Labs maybe for 175726-57-5

Nanjing Chemical Material Corp.(NCMC)

website:http://www.njchemm.com

Contact:0086-25-83172879

Address:B12 Technology and Innovation Building, Nanjing Tech University, No.5 New Model Road
Alway Chem, China

website:http://www.alwaychem.com

Contact:+86-532-8586-4000, 8586-5000

Address:NO.51, TAIPING ROAD, QINGDAO, CHINA. 266001
Zhangjiagang Golden Reach Fine Chemical Co.,LTD.

Contact:+86-512-6585 6968

Address:Changfu Road， Dongsha Chemical Industry Park, Zhangjiagang City, Jiangsu Province, China
Zhaodu Fine Chemical Plant

Contact:86-310-8067016

Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China
Suzhou SuKaiLu Chemical Technology Co., Ltd.

Contact:+86-512-62766020

Address:Floor 4, Building 1, Xinyi Pharmaceutical Valley Wisdom Industrial Park, 415 Changyang Street, Suzhou Industrial Park, Jiangsu Province

Relevant to this article

Synthesis of 2-deoxy-α- and -β-D-arabino-hexopyranosyl phosphonic acids and related compounds; analogues of early intermediates in the shikimate pathway

Doi:10.1039/P19960000431
(1996)
In situ modification of the Grubbs first generation catalyst: A highly controllable metathesis catalyst bearing tridentate Schiff base ligands

Doi:10.1016/j.molcata.2013.04.010
(2013)
Iodine-induced transannular coupling of 1,6-cyclodecadiyne

Doi:10.1016/0040-4039(96)00093-7
(1996)
A rapid and efficient approach to chiral, nonracemic aza sugars from nonsugars. A formal synthesis of 1,4-dideoxy-1,4-imino-D-lyxitol

Doi:10.1021/jo960129k
(1996)
Probing enzyme stereospecificity. Inhibition of α-chymotrypsin and subtilisin Carlsberg by chiral amine- and aminoalcohol-derivatives

Doi:10.1016/0040-4020(96)00078-6
(1996)
Colloid and nanodimensional catalysts in organic synthesis: III. Alkylation of amines with primary alcohols catalyzed by colloidal nickel and cobalt

Doi:10.1134/S1070363214050065
(2014)

Article Doi