Conformational requirements of a stereospecific three- to five-carbon ring expansion reaction

DOI: 10.1016/0040-4039(96)00022-6

Source and publish data:

Tetrahedron Letters p. 1359 - 1362 (1996)

Update date:2022-08-15

Topics: Regioselectivity Steric hindrance Reaction Mechanism Chirality transfer Bond Formation

Authors:

Hill Hill

Herndon Herndon

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Article abstract of DOI:10.1016/0040-4039(96)00022-6

Synthesis of conformationally-restricted 2-alkenylcyclopropylcarbene-chromium complexes has been accomplished, and subsequent thermal ring-expansion reactions examined. Thermolysis of conformationally-restricted carbene complexes yielded products that suggest this unique ring-expansion reaction is very dependent upon conformational effects.

Full text of DOI:10.1016/0040-4039(96)00022-6

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