Tetrahedron Letters p. 1359 - 1362 (1996)
Update date:2022-08-15
Topics: Regioselectivity Steric hindrance Reaction Mechanism Chirality transfer Bond Formation
Hill
Herndon
Synthesis of conformationally-restricted 2-alkenylcyclopropylcarbene-chromium complexes has been accomplished, and subsequent thermal ring-expansion reactions examined. Thermolysis of conformationally-restricted carbene complexes yielded products that suggest this unique ring-expansion reaction is very dependent upon conformational effects.
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Doi:10.1016/j.ejmech.2011.01.048
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