Reaction of methyl 4,5-epoxy-(2E)-pentenoate with arylcopper reagents

DOI: 10.1248/cpb.44.675

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 675 - 680 (1996)

Update date:2022-08-05

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Authors:

Nagumo Nagumo

Irie Irie

Akita Akita

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Article abstract of DOI:10.1248/cpb.44.675

The reaction of methyl 4,5-epoxy-(2E)-pentenoate (1) with various arylcopper reagents was studied. Basically, all arylcopper reagents react with 1 in SN2 fashion. However, addition of BF₃ causes reversal of the regioselectivity, which can be ra

Full text of DOI:10.1248/cpb.44.675

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