Intramolecular Heck-type reactions in aqueous medium. Dramatic change in regioselectivity

DOI: 10.1016/0040-4039(96)00253-5

Source and publish data:

Tetrahedron Letters p. 2003 - 2006 (1996)

Update date:2022-08-06

Topics:

Authors:

Lemaire-Audoire, Sandrine

Savignac, Monique

Dupuis, Christophe

Genet, Jean-Pierre

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Article abstract of DOI:10.1016/0040-4039(96)00253-5

Efficient intramolecular Heck-type cyclizations were carried out in aqueous medium using water-soluble Pd/TPPTS catalysts. Under these conditions, the generally observed exo process was reversed in favor of the regioselective formation of endo cyclized co

Full text of DOI:10.1016/0040-4039(96)00253-5

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