Journal of the Chemical Society. Perkin transactions I p. 1131 - 1136 (1995)
Update date:2022-08-06
Topics:
Harrison, Carrie-Ann
Jackson, P. Mark
Moody, Christopher J.
Williams, Jonathan M. J.
The 7-bromocyclopentaindole 3 has been converted into the hydroxybutenyl derivatives 5 and 6, and the tetrahydrofuranylidene derivative 8 in model studies towards the elaboration of paspalitrem and lolitrem type side chains.In a parallel approach, the cyclopentapyrrole 13 was converted into the fused α-pyrone 16 which acted as a pyrrole-2,3-quinodimethane, and underwent Diels-Alder reaction to give, after loss of carbon dioxide, the cyclopentaindoles 17 - 21.
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(1995)Doi:10.1002/ardp.19953280311
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