Reaction of 1,3-diselenanes with metal amides

DOI: 10.1016/0040-4039(96)00356-5

Source and publish data:

Tetrahedron Letters p. 2667 - 2670 (1996)

Update date:2022-09-26

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Authors:

Krief, Alain

Defrere, Laurent

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Article abstract of DOI:10.1016/0040-4039(96)00356-5

1,3-Diselenanes are efficiently metallated by LDA or better by KDA. On conformationally rigid derivatives, metallation is more efficient on equatorial hydrogen and leads to 2-metallo-diselenanes bearing the metal in equatorial position.

Full text of DOI:10.1016/0040-4039(96)00356-5

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