Tetrahedron Letters p. 2773 - 2776 (1996)
Update date:2022-08-03
Topics:
Domon
Vogeleisen
Uguen
Enzyme-catalysed acetylation of either syn,syn- or anti,anti-2,4-dimethyl-1,3,5-pentane triol, easily obtained from a mixture of diastereomeric 3-hydroxy-2,4-dimethylglutaric acids, proceeds stereoselectively with preferential attack of the hydromethyl group linked to the R carbon atom of the starting triol, hence providing synthons useful for preparing compounds of the polypropionic pool.
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