Synthesis of a novel chiral 1, 3-Benzoxazinone auxiliary and its application to highly diastereoselective aldol reaction

DOI: 10.1016/0040-4039(96)00508-4

Source and publish data:

Tetrahedron Letters p. 3129 - 3132 (1996)

Update date:2022-07-30

Topics:

Authors:

Miyake, Tsutomu

Seki, Masahiko

Nakamura, Yoshinori

Ohmizu, Hiroshi

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Article abstract of DOI:10.1016/0040-4039(96)00508-4

Condensation of 1-menthone with salicylamide followed by isomerization of the adduct withDBU afforded a novel chiral 1, 3-benzoxazinone auxiliary, the usefulness of which was demonstrated by highly diastereoselective aldol reaction with aldehydes. Copyright

Full text of DOI:10.1016/0040-4039(96)00508-4

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Product name:(1'''S,4'''R,2S)-(-)-2-menthonyl-3H-benzo[e][1,3]oxazin-4-one

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